介绍了碳纤维产业在中国从无到有的发展历程。中国碳纤维在产业化过程中解决了装备不足、成本偏高、应用设计能力缺乏等问题。以光威集团为例,阐释了中国企业在中国碳纤维产业发展中的突出作用。中国碳纤维研制目前面临4个问题:产业化工艺与装备核心技术仍未本质突破;碳纤维研制及应用重大基础科学问题尚未探明;大部分应用领域缺乏复合材料设计-制造-评价-考核验证能力;人才规模有限、分布不均。基于此,提出了加强高端碳纤维及其复合材料系列化和自主创新等建议。
The development process of carbon fiber industry in China is introduced. In the process of industrialization, China's carbon fiber has solved the problems of insufficient equipment, high cost and lack of application and design ability. Taking Guangwei Group as an example, the prominent role of Chinese enterprises in the development of China's carbon fiber industry is illustrated. China's carbon fiber development currently faces 4 problems:(1) Industrialization technology and equipment core technology has not yet made a breakthrough. (2) Major basic scientific issues in the development and application of carbon fibers have not yet been identified. (3) Most applications lack composite design, manufacturing, evaluation and qualification. (4) The scale of talents is limited and the distribution is uneven. Based on this, suggestions for strengthening the high-end carbon fiber and its composite materials serialization and independent innovation are put forward.
[1] 益小苏. 先进复合材料技术研究与发展[M]. 北京:国防工业出版社, 2006. Yi Xiaosu. Research and development of advanced composite technology[M]. Beijing:National Defense Industry Press, 2006.
[2] 陈祥宝. 先进树脂基复合材料的发展[J]. 航空材料学报, 2000, 20(1):46-54. Chen Xiangbao. Development of advanced resin matrix composites[J]. Journal of Aeronautical Materials, 2000, 20(1):46-54.
[3] 张跃, 陈英斌. 聚丙烯腈基碳纤维的研究进展[J]. 纤维复合材料, 2009, 26(1):7-10. Chen Yue, Chen Yingbin. Research progress of polyacrylonitrile based carbon fibers[J]. Fiber Composites, 2009, 26(1):7-10.
[4] Ghafoori E, Motavalli M. Normal high and ultra high modulus carbon fiber-reinforced polymer laminates for bonded and unbonded strengthening of steelbeams[J]. Materials & Design, 2015, 67:232-243.
[5] Schnerch D, Stanford K, Sumner E, et al. Strengthening steel structures and bridges with high-modulus carbon fiber-reinforced polymers resin selection and scaled monopole behavior[J]. Transportation Research Record:Journal of the Transportation Research Board, 2004, 1892:237-245.
[6] 赵稼祥. 民用航空和先进复合材料[J]. 高科技纤维与应用, 2007, 32(2):6-10. Zhao Jiaxiang. Civil aviation and advanced composite materials[J]. Hi-tech Fiber & Application, 2007, 32(2):6-10.
[7] 陈绍杰. 炭纤维再聚焦[J]. 高科技纤维与应用, 2009, 34(1):1-8. Chen Shaojie. Carbon fiber re-focusing[J]. Hi-tech Fiber & Application, 2009, 34(1):1-8.
[8] 李克健. 中国碳纤维研究的过去与现在[J]. 新材料产业, 2009(10):101-105. Li Kejian. Past and present of carbon fiber research in China[J]. Advanced Materials Industry, 2009(10):101-105.
[9] 徐樑华. 国产碳纤维质量状况及对策建议[J]. 新材料产业, 2010(9):5-8. Xu Lianghua. Quality status of domestic carbon fiber and countermeasures[J]. Advanced Materials Industry, 2010(9):5-8.
[10] 朱波. PAN基碳纤维制备成本构成分析及其控制探讨[J]. 新材料产业, 2010(9):36-38. Zhu Bo. Cost analysis and control of PAN based carbon fiber[J]. Advanced Materials Industry, 2010(9):36-38.
[11] 杨彦春. 三大机构经济展望报告认为:2011年世界经济缓慢而稳定增长[N]. 经济日报, 2011-01-22(5). Yang Yanchun. Three major institutions' economic outlook report says:In 2011, the world economy was growing slowly and steadily[N]. Economic Daily, 2011-01-22(5).
[12] 李舜. 碳纤维:热潮之下冷思考[N]. 中国石化报, 2010-06-22(1). Li Shun. Carbon fiber:Cool thinking under the craze[N]. China Petrochemical News, 2010-06-22(1).
[13] Gupta A, Harrison I R. New aspects in the oxidative stabilization of PAN-base carbon fibers[J]. Carbon, 1996, 34:1427-1445.
[14] Ko T, Day T, Perng J. The characterization of PAN-based carbon fibers developed by two stage continuous carbonization[J]. Carbon, 1993, 31(5):765-771.
[15] Gao A J, Su C J, Luo S, et al. Densification mechanism of polyacrylonitrile-based carbon fiber during heat treatment[J]. Journal of Physics and Chemistry of Solids, 2011, 72(10):1159-1164.
[16] Liu J, Wang P H, Li R Y. Continuous carbonization of polyacrylonitrile based oxidized fibers:Aspects on mechanical properties and morphological structure[J]. Journal of Applied Polymer Science, 1994, 52(7):945-950.
[17] Li L Y, Huang Q Z, Zhang H B. Study on the carbonization of polyacrylonitrile-based preoxidized fibres[J]. Materials Science and Engineering or Powder Metallargy, 2000, 5(1):69-74.
[18] 姜茂川, 范雨娇. 国内碳纤维产业发展浅析及展望[J]. 新材料产业, 2017(8):38-43. Jiang Maochuan, Fan Yujiao. Development and prospect of domestic carbon fiber industry[J]. Advanced Materials Industry, 2017(8):38-43.